Unsymmetrically substituted SubPhthalocyanine hybrids

Abstract

Tetrabenzotriazaporphyrins (TBTAPs) are hybrid structures between phthalocyanines and tetrabenzoporphyrins, known for their unique electronic and physical properties. However, their synthesis and purification challenges make their interest rare. This thesis explores the synthesis of SubTBDAPs, which share similar properties with PC and TBP. Key intermediates include aminoisoindolene precursors and trialkoxyborates, with boron trichloride used in a preliminary strategy.